By Maurice Morton (auth.), Maurice Morton (eds.)
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Additional info for Rubber Technology
Sample text
10 'Natural Rubber News, April 1984. bAverage prices for most common grade, December 1984. *Total for all rubbers, exluding urethanes 334,420. Total consumption,' synthetic rubbers 1,860,792 676,267 natural rubber Total consumption 2,537,059 cyclic structures are fonned. The totfil amount of sulfur combined in these networks is usually called the coefficlent of vulcanization and is defined as parts of sulfur combined,Per lOO--parts of rubber. For most rubbers, one crosslink for about each 200 monomer units in the chain is sufficient to produce a suitable vulcanized product (molecular weight between crosslinks equals ca.
The sulfur-bearing compounds used decompose at the vulcanization temperature and release radicals which combine with the chains to form crosslinks. With these systems, efficient crosslinking occurs as most of the sulfur is combined in crosslinks containing one or two sulfur atoms with little or no cyclic sulfur present. Consequently, this form of vulcanization produces products which resist aging processes at elevated temperatures much more effectively than those produced with normal curing systems.
00 specific gravity stock. Source: Farrel Company Bulletins 173E and 215. From the above examples, it is apparent that the following information concerning mixing cycles and times can be extended to practical factory or laboratory processes: 1. There are defJnite temperature ranges for mixi~ ruhbers, each specific rubber having an optimum temperature at which the desired dispersion of compounding ingredients in the mix is obtained. 2. Some rubbers require an initial breakdown period before the ingredients are added.